Firstly detergents work by breaking down the soil, emulsifying into a rinsable solution as soil is ph sensitive this is why we use high ph pre-sprays on heavily soiled carpets, then rinse with the acidic rinse to bring the PH back down.
It is essential to acid rinse wool and wool mix carpets to avoid long term damage to the fibre and prevent browning if the jute backing bleeds. The Ph of wool after cleaning should be bvetween 3 - 6.5 ideally.
However if the carpet is syntehetic, Polyprop or nylon then you can rinse with the higher PH rinses, such as Crystal green etc.
If your just starting out i would advise that you use woolsafe products if unsure Pre-spray gold been my favourite, always do a burn test and float test and check for colour bleed.
Microsplitters work in a different way to detergents, they break down the bond between the soil and the fibre, they need a long dwell time and agitation to be effective.
Mark