I would guess that the probe is after the hot water outlet of the plate exchanger in effect giving you the temp of the water being produced at the time , and the best place to be for frost stat use , the exchanger is going to break long before the burner in the event of frost .
Its the temperature probe that connects to the Spring Frostat controller.
It was plumbed into the hot outlet from the heat exchanger to the hose reel on the Heatwave. It measured the temperature of the water after it left the temperature control valve. It was inside the cabinet. When the temperature drops to 2 degrees the Froststat triggers the boiler which runs for 10 minutes. Hot water circulates through the heat exchangers and header tank before returning to the boiler for another boost of heat.
If the controller is also switched on and the hose reel connected to the van's tank, warm water will also circulate for 10 minutes to the van's tank. Either way, one side of the heat exchanger is protected against frost with antifreeze, but the warmth in the heat exchanger will also protect the other side which hasn't got antifreeze in the water.
This is a Frost stat instruction manual for an older model controller.