I actually did this for a while. And it works very well.
Hooked my IBC to the gutter outlet, and ran it directly through my DI. Problem is that we just dont get enough rainfall when you need it and i had to keep putting the ro on to top it up, and i ended up with a mossie infestation in the van last summer it was a nightmare so evenutally after 2 years of using rainwater i dismantled it and went back to ro only. Plus it makes the tank filthy green and cloudy. But no spots on windows.
To do it properly, you need to pump the rainwater through a high wattage UV system, and then through another ro again to di it into a 2nd tank before using it in your di in the van And this is costly, you might aswell not bother.
Its a bit of a ball ache. And you kinda need sustained rainfall every week.