2' x 4' sounds like an off cut laid there originally. (off gassing)
no cure, check the shape of the mark.
or Browning (fugitive dye wicking). acid rinse will cure.
probably over enthusiastic pre-spraying.
The smell is sun cooked wool, in my subbing days sold loads
of deoderiser whenever this arose, if customer refused the sale
you would spray some solution by the patio doors, wait 5 min's
then call them in to clinch the sale.