I do a few places that get the same. Why some leaded windows are more prone than others, I don't know. The odd thing is that the houses that have that problem all have mock wood upvc frames.
I spray a caustic based hard surface cleaner (strong arm, g101, etc) on either the brush head or on the glass. What ever you do make sure it's diluted at least 20 - 1 and if you spray or use too much you'll be rinsing for ages. Also, do not let it dry on the glass.