I don't think the resin will last long .... could you buy some ro water from somewhere?
As much as I know you will start producing pure water then the resin will become exhausted this depends on numerous factors like the rate of flow the depth of the resin bed the temperature of the water etc. so a slow flow and the biggest di vessel would seem sensible from this scenario.
The double di system starts with only one DI until the tds rises then introduce a second di. When that DI tds starts to rise beyond a workable level. Fill the first DI with fresh resin and swap them round rinse and repeat (seems like an appropriate expression).
Inline tds meter seems ideal for this system.
Disclaimer alert I am not sure if this is correct but seems reasonable .....
If you are going for this why not introduce some pre filters as you fill up the tank to get some of the crud out of the water may save money in the end and possibly a softener because you can just keep regenerating it. This softener would remove calcium and magnesium ions which leave white spots on glass because of their extra charge (2+) Ca2+ Mg2+ and extra willingness to bond with whatever elements are knocking around (extra sticky = extra difficult to remove with ion exchange resin)... that way you may get the cost down it's worth experimenting it could be the future and you could have a USP of not being a water waster window washer!
I also read that it's a no-no to let the waste from an RO unit go down the drain
but that was on a night time info trawl when I had had a couple of belgian beers so may be incorrect info (I was looking at a water authority site during the drought). Any opinions anyone?