I read mention on a couple of occasions of people saying how water either begins to freeze a 3 degrees, or it is less dense when hot, more dense when cold and so on.
Water is strange stuff, it doesn't behave in the way you might expect it to, water may be less dense when it is steam, although if you could measure the density of each individual droplet of steam that would change!
When water is cold it becomes less dense (ice).
For the sake of experiment I poured very precisely, 1 pint of ice cold water into a kettle.
I then brought said pint of water to the boil, pouring it quickly into the measuring jug.
If it was less dense then that pint of water should have expanded and be showing as more than a pint of water...it wasn't...it was still on exactly the same line, if there was any difference it wasn't enough to be able to notice with the naked eye.
When other things get hot they expand, it isn't until water boils and turns to steam that it changes...
Hot water DOES make a difference when cleaning, be it windows or the washing up, but it is the way in which the grime reacts to heat that is making the biggest difference, it softens and changes the properties of whatever substance you are trying to disolve....
I'm no scientist I know, so I'm also going to do a bit of googling about the properties of water, apparently it still baffles scientists with its varies properties, it hates to change it's state!
The amount of energy needed to bring water to the boil is totally disproportionate to what would actually be expected from a substance with the 'apparent' properties that you might expect water to actually have....as I understand it anyway! :
Ian