Good idea in principle.
Not very practical though unless....... you store it into a large container and then pump it direct through a DI. It should be at a low TDS so maybe not worth putting it through an RO. You will need to pump it though.
To store rain water to go through RO really isnt worth the hassle. You probably cant store a worthwhile amount and you will have to get your pressure up to around 50 PSI so you will need a decent pump to do this.
But... Like Morph says dont feel silly about making any suggestions or asking questions.
There's a wealth of knowledge and experience here and the answers
( USUALLY ) are great... and some are just a total HOOT!!
Andrew ( smellin of dog doo doo that I fell into today ) Grrrrrrr