I go with Mike on temperature for wool. I seem to remember reading in, I think, one of Eric Brown's books, that wool, although sensitive to higher temperatures, is only exposed to it for a mere moment, so for our purposes, he considers temperature irrelevant re. safety.
As for Paul, I would go along with the others re. training. The NCCA would be my first choice course, but there are other excellent courses available. The ones that spring to mind are Prochem, Chemspec and IICRC. As is often the case, geography may dictate which one you use.