Brasso, solvol autosolv, brown sauce, or for the pc and tree hugging brigade a phosphoric free substitute
i remember dripping some HF acid on some copper roof once when i was cleaning the bricks, turned it from black/green, back to bright copper...but im guessing its not healthy for the copper in big doses..
is it defo green paint? Because i think copper turns green when it's been oxidised (exposed to the atmosphere and water) maybe it could be that? just a guess